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Potatoes exposed to light may develop a greenish color due to the presence of chlorophyll. Chlorophyll is a pigment responsible for the green color in plants and is typically found in leaves where photosynthesis occurs. When potatoes are exposed to light, especially sunlight, they start producing chlorophyll as a natural response. This chlorophyll production leads to the green coloration of the exposed areas of the potato. However, the green parts of the potato also contain a compound called solanine, which develops concurrently with chlorophyll and can be toxic in high concentrations. Therefore, it's important to avoid consuming potatoes with green spots or to cut away any green areas before consumption to reduce the risk of solanine poisons.

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