What amount in moles of a strong acid such
as HBr must be dissolved in 1.00 L of water
to prepare a solution whose pH is 2.00?



Answer :

To solve this problem, we need to determine the amount of hydrogen bromide (HBr) required to achieve the desired pH of the solution. Let's break it down step by step.

### Step 1: Understand the Relationship Between pH and [H⁺]

The pH of a solution is given by the formula:
[tex]\[ \text{pH} = -\log[\text{H}^+] \][/tex]

Where:
- [tex]\([\text{H}^+]\)[/tex] is the concentration of hydrogen ions in the solution in moles per liter (M).

### Step 2: Calculate the Hydrogen Ion Concentration

We are given that the pH of the solution should be 2.00. Using the pH formula, we can determine the concentration of hydrogen ions [tex]\([\text{H}^+]\)[/tex].

[tex]\[ \text{pH} = 2.00 \implies -\log[\text{H}^+] = 2.00 \][/tex]

To find [tex]\([\text{H}^+]\)[/tex], we need to rearrange the formula:

[tex]\[ [\text{H}^+] = 10^{-\text{pH}} \][/tex]

Plugging in the given pH:

[tex]\[ [\text{H}^+] = 10^{-2.00} \][/tex]

Calculating this:

[tex]\[ [\text{H}^+] = 0.01 \, \text{M} \][/tex]

### Step 3: Relate [H⁺] to the Amount of HBr

Hydrogen bromide (HBr) is a strong acid, which means it completely dissociates in water. This means every mole of HBr added to the water will produce one mole of [tex]\(\text{H}^+\)[/tex] ions. Therefore, the concentration of HBr needed is equal to the concentration of [tex]\(\text{H}^+\)[/tex] ions required.

So, [tex]\([\text{HBr}] = [\text{H}^+] = 0.01 \, \text{M}\)[/tex].

### Step 4: Calculate the Amount of HBr in Moles

The concentration calculated above is in moles per liter (M). Since we are preparing 1.00 L of solution, the amount in moles of HBr required will be equivalent to its concentration.

[tex]\[ \text{Amount of HBr (in moles)} = \text{Volume of solution (in L)} \times \text{Concentration (in M)} \][/tex]

Given that the volume of the solution is 1.00 L:

[tex]\[ \text{Amount of HBr} = 1.00 \, \text{L} \times 0.01 \, \text{M} = 0.01 \, \text{moles} \][/tex]

### Final Answer:

The amount of HBr that must be dissolved in 1.00 L of water to prepare a solution whose pH is 2.00 is [tex]\(0.01\)[/tex] moles.