Final answer:
In five instances, popular-vote winners did not become presidents due to Electoral College outcomes.
Explanation:
The popular-vote winner has not been elected president because they did not win a majority in the Electoral College on five occasions. This occurred in the elections of 1824, 1876, 1888, 2000, and 2016. Candidates like Al Gore and Hillary Clinton won the popular vote but lost the presidency due to the Electoral College system.
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