Select the correct answer.

A solution has a pH of 4.20. Using the relationship between pH and pOH, what is the concentration of [tex]\( OH^{-} \)[/tex]?

A. [tex]\( 9.9 \times 10^{-1} \, M \)[/tex]
B. [tex]\( 6.2 \times 10^{-1} \, M \)[/tex]
C. [tex]\( 6.3 \times 10^{-5} \, M \)[/tex]
D. [tex]\( 6.7 \times 10^{-6} \, M \)[/tex]
E. [tex]\( 1.6 \times 10^{-10} \, M \)[/tex]



Answer :

Let's solve this step-by-step from the given information.

1. Given Information:
- The solution has a [tex]\( \text{pH} \)[/tex] of 4.20.

2. Relationship Between pH and pOH:
- We know that the sum of [tex]\( \text{pH} \)[/tex] and [tex]\( \text{pOH} \)[/tex] is 14.
[tex]\[ \text{pH} + \text{pOH} = 14 \][/tex]
- Substituting the given [tex]\( \text{pH} \)[/tex]:
[tex]\[ 4.20 + \text{pOH} = 14 \][/tex]
- Solving for [tex]\( \text{pOH} \)[/tex]:
[tex]\[ \text{pOH} = 14 - 4.20 = 9.80 \][/tex]

3. Calculating the Concentration of OH⁻ Ion:
- The concentration of [tex]\( \text{OH}^- \)[/tex] is related to [tex]\( \text{pOH} \)[/tex] by the formula:
[tex]\[ \text{[OH}^-] = 10^{-\text{pOH}} \][/tex]
- Substituting the value of [tex]\( \text{pOH} \)[/tex]:
[tex]\[ \text{[OH}^-] = 10^{-9.80} \][/tex]
- Using exponential calculation (approximated):
[tex]\[ \text{[OH}^-] \approx 1.584893192461111 \times 10^{-10} \, M \][/tex]

4. Select the Closest Answer:
From the given options:
- A. [tex]\( 9.9 \times 10^{-1} \, M \)[/tex]
- B. [tex]\( 6.2 \times 10^{-1} \, M \)[/tex]
- C. [tex]\( 6.3 \times 10^{-5} \, M \)[/tex]
- D. [tex]\( 6.7 \times 10^{-6} \, M \)[/tex]
- E. [tex]\( 1.6 \times 10^{-10} \, M \)[/tex]

The calculated concentration [tex]\(\left(1.584893192461111 \times 10^{-10} \, M\right)\)[/tex] is closest to:
[tex]\[ \text{E. } 1.6 \times 10^{-10} \, M \][/tex]

Therefore, the correct answer is:
[tex]\[ \boxed{E. \quad 1.6 \times 10^{-10} \, M} \][/tex]

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