Determine if the reaction absorbed or released heat.

4 Fe + 3 O₂ + xH₂O → 2 Fe₂O₃ · xH₂O

The formation of rust (equation above) is an example of both combustion and ________.



Answer :

Sure, let’s delve into the formation of rust, describe the process in detail, and identify the different types of chemical reactions it involves.

Rust forms when iron undergoes a chemical reaction with oxygen and water, typically from the atmosphere. This can be represented by the following chemical equation:

[tex]\[ 4 \text{Fe} + 3 \text{O}_2 + x \text{H}_2\text{O} \rightarrow 2 \text{Fe}_2\text{O}_3 \cdot x \text{H}_2\text{O} \][/tex]

### Step-by-Step Solution:

1. Components Involved:
- Iron (Fe): This is the metal that’s prone to oxidation.
- Oxygen (O₂): Present in the air, this gas reacts with iron.
- Water (H₂O): Water from the environment is crucial for rust formation.

2. Type of Reaction - Combustion:
- Combustion typically refers to a reaction where a substance (often a hydrocarbon) reacts rapidly with oxygen to release energy. This reaction, while slower, is a type of oxidation similar to combustion.

3. Type of Reaction - Oxidation-Reduction (Redox):
- The rusting process is a classic example of an oxidation-reduction reaction.
- Oxidation: Iron (Fe) loses electrons. Iron in Fe changes from zero-valent (Fe⁰) to a +3 oxidation state in Fe³⁺.
- Reduction: Oxygen gains electrons, going from an oxidation state of 0 in O₂ to -2 in H₂O and Fe₂O₃.

4. Water's Role:
- Water acts as a medium that facilitates the transfer of electrons between iron and oxygen. It also plays a role in the hydrolysis of iron ions.

This chemical process can also be considered an example of hydration because the rust ( [tex]\(\text{Fe}_2\text{O}_3 \cdot x\text{H}_2\text{O}\)[/tex]) includes water molecules in its structure.

### Conclusion:
The formation of rust involves iron reacting with oxygen and water, leading to the formation of hydrated iron(III) oxide. This process is an example of both combustion and oxidation-reduction. It’s a slow form of combustion, but technically it still fits the definition because of its nature of reacting with oxygen. Also, the inclusion of water molecules in the rust (hydration) makes it an example of hydration as well.

Therefore, the formation of rust is an example of both combustion and oxidation-reduction (redox) reactions.