The energy diagram shown represents the chemical reaction between solid ammonium chloride and solid barium hydroxide octahydrate:
[tex]\[ 2 \text{NH}_4 \text{Cl} (s) + \text{Ba(OH)}_2 \cdot 8 \text{H}_2 \text{O} (s) \rightarrow 2 \text{NH}_3 (aq) + \text{BaCl}_2 (aq) + 10 \text{H}_2 \text{O} (l) \][/tex]

The [tex]\(\Delta H\)[/tex] for this reaction is [tex]\(54.8 \, \text{kJ}\)[/tex]. How much energy would be absorbed if [tex]\(26.3 \, \text{g}\)[/tex] of [tex]\(\text{NH}_4 \text{Cl}\)[/tex] reacts?



Answer :

To determine how much energy would be absorbed if 26.3 grams of ammonium chloride (NH₄Cl) reacts, we need to follow these steps:

1. Determine the number of moles of NH₄Cl:

- The molar mass of NH₄Cl (ammonium chloride) is given as 53.49 g/mol.

- The mass of NH₄Cl is given as 26.3 grams.

- We use the formula for the number of moles:
[tex]\[ \text{moles of NH}_4\text{Cl} = \frac{\text{mass of NH}_4\text{Cl}}{\text{molar mass of NH}_4\text{Cl}} \][/tex]
[tex]\[ \text{moles of NH}_4\text{Cl} = \frac{26.3\text{ g}}{53.49\text{ g/mol}} \][/tex]

Calculating this gives:
[tex]\[ \text{moles of NH}_4\text{Cl} \approx 0.4917 \text{ mol} \][/tex]

2. Determine the energy absorbed:

- The enthalpy change [tex]$\Delta H$[/tex] for the reaction is given as 54.8 kJ per mole of the reaction.

- Since the balanced chemical equation shows that 2 moles of NH₄Cl are involved in the reaction, we need to find the energy absorbed for the moles of NH₄Cl we calculated.

- We use the formula to calculate the energy absorbed:
[tex]\[ \text{Energy absorbed} = \text{moles of NH}_4\text{Cl} \times \Delta H \][/tex]
[tex]\[ \text{Energy absorbed} = 0.4917 \text{ mol} \times 54.8\text{ kJ/mol} \][/tex]

Calculating this gives:
[tex]\[ \text{Energy absorbed} \approx 26.9441 \text{ kJ} \][/tex]

Therefore, if 26.3 grams of NH₄Cl reacts, approximately 26.9441 kJ of energy would be absorbed.