Amylose has a-1,4-glycosidic bonds, while both amylopectin and glycogen have a-1,6-glycosidic bonds in addition to a-1,4-glycosidic bonds.
Amylose contains a-1,4-glycosidic bonds, making it a linear chain of a-D-glucose units. On the other hand, amylopectin has both a-1,4- and a-1,6-glycosidic bonds, with the branch points linked through a-1,6-linkages. Glycogen also contains branch points that are linked through a-1,6-linkages.
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