Final answer:
Leonardo da Vinci's famous work commissioned by the Catholic Church is The Last Supper, depicting the last meal shared by Jesus and his disciples.
Explanation:
The famous work by Leonardo da Vinci commissioned by the Catholic Church is The Last Supper. This iconic fresco depicts the last meal Jesus shared with his 12 Apostles, where he announces one of them will betray him. The painting is located in Milan's Monastery Maria delle Grazie.
Learn more about Leonardo da Vinci's artwork here:
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