Which of these solutions is the most acidic?

A. [tex]$\left[ \text{OH}^{-}\right]=2 \times 10^{-12} \, M$[/tex]
B. [tex]$\left[ \text{OH}^{-}\right]=3 \times 10^{-3} \, M$[/tex]
C. [tex]$\left[ \text{H}_3\text{O}^{+}\right]=4 \times 10^{-4} \, M$[/tex]
D. [tex]$\left[ \text{H}_3\text{O}^{+}\right]=6 \times 10^{-6} \, M$[/tex]



Answer :

To determine which solution is the most acidic, we need to identify which one has the highest concentration of hydronium ions [tex]\([H_3O^+]\)[/tex]. The higher the concentration of hydronium ions, the more acidic the solution is.

We are given four different concentrations:

- Two concentrations of hydroxide ions [tex]\([OH^-]\)[/tex]:
1. [tex]\([OH^-] = 2 \times 10^{-12} \text{M}\)[/tex]
2. [tex]\([OH^-] = 3 \times 10^{-3} \text{M}\)[/tex]

- Two concentrations of hydronium ions [tex]\([H_3O^+]\)[/tex]:
1. [tex]\([H_3O^+] = 4 \times 10^{-4} \text{M}\)[/tex]
2. [tex]\([H_3O^+] = 6 \times 10^{-6} \text{M}\)[/tex]

For the given [tex]\([OH^-]\)[/tex] concentrations, we need to convert them to [tex]\([H_3O^+]\)[/tex] using the relationship:
[tex]\[ [H_3O^+] \times [OH^-] = 1 \times 10^{-14} \][/tex]

Let's calculate the [tex]\([H_3O^+]\)[/tex] concentrations:

1. For [tex]\([OH^-] = 2 \times 10^{-12} \text{M}\)[/tex]:
[tex]\[ [H_3O^+] = \frac{1 \times 10^{-14}}{2 \times 10^{-12}} = \frac{1 \times 10^{-14}}{2 \times 10^{-12}} = 0.005 \text{M} \][/tex]

2. For [tex]\([OH^-] = 3 \times 10^{-3} \text{M}\)[/tex]:
[tex]\[ [H_3O^+] = \frac{1 \times 10^{-14}}{3 \times 10^{-3}} = \frac{1 \times 10^{-14}}{0.003} \approx 3.333 \times 10^{-12} \text{M} \][/tex]

Now, we have four [tex]\([H_3O^+]\)[/tex] concentrations:

1. From [tex]\([OH^-] = 2 \times 10^{-12} \text{M}\)[/tex]: [tex]\([H_3O^+] = 0.005 \text{M}\)[/tex]
2. From [tex]\([OH^-] = 3 \times 10^{-3} \text{M}\)[/tex]: [tex]\([H_3O^+] \approx 3.333 \times 10^{-12} \text{M}\)[/tex]
3. Given directly: [tex]\([H_3O^+] = 4 \times 10^{-4} \text{M}\)[/tex]
4. Given directly: [tex]\([H_3O^+] = 6 \times 10^{-6} \text{M}\)[/tex]

To find the most acidic solution, we compare these [tex]\([H_3O^+]\)[/tex] concentrations:

- [tex]\(0.005 \text{M}\)[/tex]
- [tex]\(3.333 \times 10^{-12} \text{M}\)[/tex]
- [tex]\(4 \times 10^{-4} \text{M}\)[/tex]
- [tex]\(6 \times 10^{-6} \text{M}\)[/tex]

Clearly, the highest [tex]\([H_3O^+]\)[/tex] concentration is [tex]\(0.005 \text{M}\)[/tex].

Therefore, the solution with [tex]\([OH^-] = 2 \times 10^{-12} \text{M}\)[/tex] is the most acidic.