Sodium carbonate and sulfuric acid react to produce sodium sulfate, carbon dioxide, and water according to the balanced chemical equation:

[tex]\[ \text{Na}_2 \text{CO}_3(aq) + \text{H}_2 \text{SO}_4(aq) \rightarrow \text{Na}_2 \text{SO}_4(aq) + \text{CO}_2(g) + \text{H}_2 \text{O}(l) \][/tex]

What volume of carbon dioxide gas can be produced from the complete reaction of 0.690 L of 1.50 M sulfuric acid? The temperature and pressure of the reaction are 298 K and 0.98 atm, respectively.

A. 26 L
B. 0.69 L
C. 37 L
D. 1.04 L



Answer :

To solve this problem, let’s break it down into clear steps:

1. Calculate the moles of sulfuric acid (H₂SO₄):

The molarity (M) of H₂SO₄ is given as 1.50 M, and the volume of H₂SO₄ we have is 0.690 L.

Using the formula:

[tex]\[ \text{Moles of H₂SO₄} = \text{Molarity} \times \text{Volume} \][/tex]

[tex]\[ \text{Moles of H₂SO₄} = 1.50 \times 0.690 = 1.035 \text{ moles} \][/tex]

2. Determine the moles of carbon dioxide (CO₂) produced:

According to the balanced chemical equation provided:

[tex]\[ Na_2CO_3 + H_2SO_4 \rightarrow Na_2SO_4 + CO_2 + H_2O \][/tex]

The reaction shows that 1 mole of H₂SO₄ produces 1 mole of CO₂.

Hence, the moles of CO₂ produced will be equal to the moles of H₂SO₄ reacted:

[tex]\[ \text{Moles of CO₂} = 1.035 \text{ moles} \][/tex]

3. Calculate the volume of CO₂ gas produced using the Ideal Gas Law:

The Ideal Gas Law is:

[tex]\[ PV = nRT \][/tex]

Where:
- [tex]\(P\)[/tex] is the pressure (in atm)
- [tex]\(V\)[/tex] is the volume (in L)
- [tex]\(n\)[/tex] is the number of moles
- [tex]\(R\)[/tex] is the ideal gas constant (0.0821 L·atm/(K·mol))
- [tex]\(T\)[/tex] is the temperature (in K)

Rearranging the Ideal Gas Law to solve for the volume ([tex]\(V\)[/tex]):

[tex]\[ V = \frac{nRT}{P} \][/tex]

Substituting the given values:
- [tex]\(n = 1.035\)[/tex] moles
- [tex]\(R = 0.0821\)[/tex] L·atm/(K·mol)
- [tex]\(T = 298\)[/tex] K
- [tex]\(P = 0.98\)[/tex] atm

[tex]\[ V = \frac{1.035 \times 0.0821 \times 298}{0.98} \][/tex]

[tex]\[ V \approx 25.838880612244896 \text{ L} \][/tex]

4. Compare the calculated volume to the given options:

The possible answers are:
- 26 L
- 0.69 L
- 37 L
- 1.04 L

The calculated value, 25.838880612244896 L, is closest to 26 L.

Therefore, the volume of carbon dioxide gas produced from the complete reaction is 26 L.