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Aqueous sulfuric acid [tex]\(\left( H_2SO_4 \right)\)[/tex] will react with solid sodium hydroxide [tex]\(\left( NaOH \right)\)[/tex] to produce aqueous sodium sulfate [tex]\(\left( Na_2SO_4 \right)\)[/tex] and liquid water [tex]\(\left( H_2O \right)\)[/tex]. Suppose 16.0 g of sulfuric acid is mixed with 6.14 g of sodium hydroxide. Calculate the maximum mass of water that could be produced by the chemical reaction. Round your answer to 3 significant digits.



Answer :

Let's solve the problem of determining the maximum mass of water that could be produced by the reaction between sulfuric acid ([tex]\( \text{H}_2 \text{SO}_4 \)[/tex]) and sodium hydroxide ([tex]\( \text{NaOH} \)[/tex]).

1. Write the balanced chemical equation:

[tex]\[ \text{H}_2 \text{SO}_4 + 2 \text{NaOH} \rightarrow \text{Na}_2 \text{SO}_4 + 2 \text{H}_2 \text{O} \][/tex]

2. Determine the molar masses:
- Molar mass of [tex]\( \text{H}_2 \text{SO}_4 \)[/tex]:
[tex]\[ 2(1.01) + 32.07 + 4(16.00) = 98.08 \text{ g/mol} \][/tex]
- Molar mass of [tex]\( \text{NaOH} \)[/tex]:
[tex]\[ 22.99 + 15.999 + 1.01 = 40.00 \text{ g/mol} \][/tex]
- Molar mass of [tex]\( \text{H}_2 \text{O} \)[/tex]:
[tex]\[ 2(1.01) + 16.00 = 18.015 \text{ g/mol} \][/tex]

3. Calculate the number of moles of each reactant:
- Moles of [tex]\( \text{H}_2 \text{SO}_4 \)[/tex] (given 16.0 g):
[tex]\[ \frac{16.0 \text{ g}}{98.08 \text{ g/mol}} = 0.163 \text{ mol} \][/tex]
- Moles of [tex]\( \text{NaOH} \)[/tex] (given 6.14 g):
[tex]\[ \frac{6.14 \text{ g}}{40.00 \text{ g/mol}} = 0.1535 \text{ mol} \][/tex]

4. Identify the limiting reactant:
- According to the stoichiometry, 1 mole of [tex]\( \text{H}_2 \text{SO}_4 \)[/tex] reacts with 2 moles of [tex]\( \text{NaOH} \)[/tex].
- Moles of [tex]\( \text{NaOH} \)[/tex] required for 0.163 mol [tex]\( \text{H}_2 \text{SO}_4 \)[/tex]:
[tex]\[ 0.163 \text{ mol} \times 2 = 0.326 \text{ mol} \][/tex]
- Since 0.1535 mol of [tex]\( \text{NaOH} \)[/tex] is given, it is less than 0.326 mol, making [tex]\( \text{NaOH} \)[/tex] the limiting reactant.

5. Calculate the moles of water produced:
- According to the reaction, 2 moles of [tex]\( \text{NaOH} \)[/tex] produce 2 moles of [tex]\( \text{H}_2 \text{O} \)[/tex].
- Moles of [tex]\( \text{H}_2 \text{O} \)[/tex] produced by 0.1535 mol of [tex]\( \text{NaOH} \)[/tex]:
[tex]\[ \frac{0.1535 \text{ mol}}{2} = 0.07675 \text{ mol} \][/tex]

6. Calculate the mass of water produced:
- Using the molar mass of [tex]\( \text{H}_2 \text{O} \)[/tex]:
[tex]\[ 0.07675 \text{ mol} \times 18.015 \text{ g/mol} = 1.38 \text{ g} \][/tex]

Thus, the maximum mass of water that could be produced by the chemical reaction is 1.38 g (rounded to 3 significant digits).