Which one of the following substances will not have hydrogen bonding as one of its intermolecular forces?

A. [tex]\(\text{CH}_3-\text{C}-\text{CH}_3\)[/tex] \\
\ \ \ \ \ \ \ H \ \ \ H

B. [tex]\(\text{OH}-\text{C}-\text{N}\)[/tex] \\
\ \ \ \ \ \ \ / \ \ \ \ | \ \ \ \ \ \ \ \ \\
\ \ \ \ \ H \ \ \ H

C. [tex]\(\text{N}-\text{N}\)[/tex] \\
\ \ \ \ H \ \ \ H

D. [tex]\(\text{OH}-\text{O}-\text{O}-\text{H}\)[/tex]

E. [tex]\(\text{CH}_3-\text{C}-\text{O}-\text{H}\)[/tex] \\
\ \ \ \ \ \ \ H \ \ \ H



Answer :

To determine which substance will not have hydrogen bonding as one of its intermolecular forces, we need to look for the presence of nitrogen-hydrogen (N-H), oxygen-hydrogen (O-H), or fluorine-hydrogen (F-H) bonds, which are necessary for hydrogen bonding.

Let's analyze each substance individually:

1. CH3-C-CH3 (Acetone):
- Structure: CH3-C(=O)-CH3
- Contains C=O double bond.
- No N-H, O-H, or F-H bonds are present.
- Conclusion: Does not have hydrogen bonding.

2. H H
OH-C-N
/|\\
H H
- Contains both O-H and N-H bonds.
- Conclusion: Has hydrogen bonding.

3. H N-N H
H
- Contains N-H bonds.
- Conclusion: Has hydrogen bonding.

4. OH-0-0-H (Hydrogen Peroxide):
- Structure: H-O-O-H
- Contains O-H bonds.
- Conclusion: Has hydrogen bonding.

5. CH3-C-O-H (Acetic Acid):
- Structure: CH3COOH
- Contains O-H bonds.
- Conclusion: Has hydrogen bonding.

6. CIM:
- Structure and bonding are unclear; let's set this aside for now.

Given this analysis, the only substance that does not have hydrogen bonding due to the absence of N-H, O-H, or F-H bonds is CH3-C-CH3 (Acetone), which corresponds to the first option in the list.

Therefore, the substance that will not have hydrogen bonding as one of its intermolecular forces is:

CH3-C-CH3 (Acetone)

This corresponds to the given result of 0, meaning the correct answer is position 0 in the list, which aligns with the substance Acetone.