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Question 42 (1 point)

The equilibrium system shown below was analyzed and the concentrations of [tex]\(HI(g)\)[/tex], [tex]\(H_2(g)\)[/tex], and [tex]\(I_2(g)\)[/tex] were found to be [tex]\(4.4\ \text{mol/L}\)[/tex], [tex]\(3.2\ \text{mol/L}\)[/tex], and [tex]\(1.5\ \text{mol/L}\)[/tex] respectively. The equilibrium constant must be which of the following?

[tex]\[ H_2(g) + I_2(g) \leftrightarrow 2 HI(g) + 65 \ \text{kJ} \][/tex]

A. 1.1
B. 4.0
C. 0.16
D. 0.92



Answer :

To solve this problem, we will use the concept of the equilibrium constant, denoted as [tex]\( K \)[/tex]. The equilibrium constant expression depends on the balanced chemical equation of the reaction.

Given the reaction equation:
[tex]\[ H_2(g) + I_2(g) \rightleftharpoons 2 HI(g) \][/tex]

The equilibrium constant expression for this reaction is:
[tex]\[ K = \frac{[HI]^2}{[H_2][I_2]} \][/tex]

Where:
- [tex]\([HI]\)[/tex] is the concentration of hydrogen iodide at equilibrium,
- [tex]\([H_2]\)[/tex] is the concentration of hydrogen gas at equilibrium,
- [tex]\([I_2]\)[/tex] is the concentration of iodine gas at equilibrium.

The given equilibrium concentrations are:
- [tex]\([HI] = 4.4 \, \text{mol/L}\)[/tex]
- [tex]\([H_2] = 3.2 \, \text{mol/L}\)[/tex]
- [tex]\([I_2] = 1.5 \, \text{mol/L}\)[/tex]

Substituting these values into the equilibrium constant expression gives us:
[tex]\[ K = \frac{(4.4)^2}{(3.2)(1.5)} \][/tex]

Now, calculate the numerator and denominator separately:
- The numerator is [tex]\((4.4)^2 = 19.36\)[/tex]
- The denominator is [tex]\((3.2) \times (1.5) = 4.8\)[/tex]

Thus:
[tex]\[ K = \frac{19.36}{4.8} \approx 4.033333333333333 \][/tex]

Since the calculated value of [tex]\(K\)[/tex] is approximately [tex]\(4.03\)[/tex], the equilibrium constant for this system matches the value of 4.0 from the choices given.

Therefore, the correct answer is:
[tex]\[ \boxed{4.0} \][/tex]