Hydrogen reacts with chlorine to form hydrogen chloride [tex] \left( HCl(g), \Delta H_f = -92.3 \, \text{kJ/mol} \right) [/tex] according to the reaction:

[tex] H_2(g) + Cl_2(g) \rightarrow 2HCl(g) [/tex]

Which statement is correct?

Use [tex] \Delta H_{\text{reaction}} = \sum\left(\Delta H_{\text{i, products}}\right) - \sum\left(\Delta H_{\text{f, reactants}}\right) [/tex].

A. The enthalpy of the reaction is -184.6 kJ, and the reaction is exothermic.
B. The enthalpy of the reaction is -184.6 kJ, and the reaction is endothermic.
C. The enthalpy of the reaction is 184.6 kJ, and the reaction is endothermic.
D. The enthalpy of the reaction is 184.6 kJ, and the reaction is exothermic.

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Answer :

Let's analyze the given problem step by step based on the provided information.

1. Balanced Chemical Equation:
The balanced chemical equation is:
[tex]\[ H_2(g) + Cl_2(g) \rightarrow 2 HCl(g) \][/tex]

2. Enthalpy of Formation:
The enthalpy of formation of hydrogen chloride (HCl) gas is given as:
[tex]\[ \Delta H_f = -92.3 \, \text{kJ/mol} \][/tex]

3. Number of Moles:
From the balanced chemical equation, we can see that 2 moles of HCl are produced.

4. Calculation of the Enthalpy Change of the Reaction:
Using the formula to calculate the total enthalpy change:
[tex]\[ \Delta H_{\text{reaction}} = \sum \left(\Delta H_{i,\text{products}} \right) - \sum \left(\Delta H_{i,\text{reactants}} \right) \][/tex]

Since [tex]\( H_2 \)[/tex] and [tex]\( Cl_2 \)[/tex] are elements in their standard state, their enthalpies of formation are zero. Therefore, we only need to consider the products:
[tex]\[ \Delta H_{\text{reaction}} = 2 \times (-92.3 \, \text{kJ/mol}) = -184.6 \, \text{kJ} \][/tex]

5. Nature of the Reaction:
The enthalpy change of the reaction is negative ([tex]\( \Delta H_{\text{reaction}} = -184.6 \, \text{kJ} \)[/tex]). A negative enthalpy change indicates that the reaction releases energy to the surroundings, thus it is exothermic.

Summarizing our findings:
- The enthalpy of the reaction is [tex]\(-184.6 \, \text{kJ}\)[/tex].
- The reaction is exothermic because it releases heat energy.

Based on this analysis, the correct statement is:
- The enthalpy of the reaction is [tex]\(-184.6 \, \text{kJ}\)[/tex], and the reaction is exothermic.

Therefore, the correct statement is:

The enthalpy of the reaction is -184.6 kJ, and the reaction is exothermic.