Balance the chemical equation below using the smallest possible whole number stoichiometric coefficients.

[tex]\[ CH_3(CH_2)_2CH_3(g) + O_2(g) \rightarrow CO_2(g) + H_2O(g) \][/tex]



Answer :

To balance the chemical equation:
[tex]\[ CH_3(CH_2)_2CH_3(g) + O_2(g) \rightarrow CO_2(g) + H_2O(g) \][/tex]

We'll use the stoichiometric coefficients to ensure that the number of atoms of each element on the reactants side equals the number on the products side.

### Step-by-Step Solution:

1. Write the unbalanced equation:
[tex]\[ CH_3(CH_2)_2CH_3 + O_2 \rightarrow CO_2 + H_2O \][/tex]

2. Identify the number of each type of atom in the unbalanced equation:

- For [tex]\(CH_3(CH_2)_2CH_3\)[/tex]:
- Carbon (C): [tex]\(3\)[/tex] from [tex]\(CH_3\)[/tex] + [tex]\(2 \times 2\)[/tex] from [tex]\((CH_2)\)[/tex] + [tex]\(1\)[/tex] from [tex]\(CH_3\)[/tex] = [tex]\(8\)[/tex] carbons.
- Hydrogen (H): [tex]\(3\)[/tex] from first [tex]\(CH_3\)[/tex] + [tex]\(2 \times 2\)[/tex] from two middle [tex]\(CH_2\)[/tex] + [tex]\(3\)[/tex] from last [tex]\(CH_3\)[/tex] = [tex]\(18\)[/tex] hydrogens.

- For [tex]\(O_2\)[/tex]:
- Oxygen (O): [tex]\(2\)[/tex] oxygens.

3. Write the number of atoms of each element needed to balance:

- For [tex]\(CO_2\)[/tex]:
- Each [tex]\(CO_2\)[/tex] has [tex]\(1\)[/tex] carbon and [tex]\(2\)[/tex] oxygens.
- For [tex]\(H_2O\)[/tex]:
- Each [tex]\(H_2O\)[/tex] has [tex]\(2\)[/tex] hydrogens and [tex]\(1\)[/tex] oxygen.

4. Set up the equations based on atom count balance:

To balance the carbon atoms:
[tex]\[ 8 \ \textrm{carbons} \rightarrow 8\ CO_2 \][/tex]

To balance the hydrogen atoms:
[tex]\[ 18 \ \textrm{hydrogens} \rightarrow 9\ H_2O \][/tex]

5. Determine the number of oxygen atoms required on the products side:

- From [tex]\(8\ CO_2\)[/tex], we have [tex]\(8 \times 2 = 16\)[/tex] oxygens.
- From [tex]\(9\ H_2O\)[/tex], we have [tex]\(9 \times 1 = 9\)[/tex] oxygens.

Total oxygens needed on the products side:
[tex]\[ 16 + 9 = 25\ \textrm{oxygens} \][/tex]

Therefore:
[tex]\[ \frac{25}{2}\ O_2 \][/tex]

6. Write the balanced equation using these coefficients:

The coefficients we have are [tex]\(1\)[/tex] for [tex]\(CH_3(CH_2)_2CH_3\)[/tex], [tex]\(\frac{25}{2}\)[/tex] for [tex]\(O_2\)[/tex], [tex]\(8\)[/tex] for [tex]\(CO_2\)[/tex], and [tex]\(9\)[/tex] for [tex]\(H_2O\)[/tex].

7. Convert fraction coefficients to whole numbers by multiplying through by [tex]\(2\)[/tex]:

[tex]\[ 2 \left[ CH_3(CH_2)_2CH_3 + \frac{25}{2} O_2 \rightarrow 8 CO_2 + 9 H_2O \right] \][/tex]

Yields:
[tex]\[ 2\ CH_3(CH_2)_2CH_3 + 25\ O_2 \rightarrow 16\ CO_2 + 18\ H_2O \][/tex]

Thus, the balanced equation is:
[tex]\[ 2\ CH_3(CH_2)_2CH_3 + 25\ O_2 \rightarrow 16\ CO_2 + 18\ H_2O \][/tex]