20. If a buffer solution is 0.210 M in a weak acid [tex]\(\left(K_{a} = 3.0 \times 10^{-5}\right)\)[/tex] and 0.480 M in its conjugate base, what is the pH?

[tex]\[
\text{pH} =
\][/tex]



Answer :

Certainly! Let's solve the problem step-by-step.

Given:
- The concentration of the weak acid, [tex]\([HA]\)[/tex], is 0.210 M.
- The concentration of the conjugate base, [tex]\([A^-]\)[/tex], is 0.480 M.
- The acid dissociation constant, [tex]\(K_a\)[/tex], is [tex]\(3.0 \times 10^{-5}\)[/tex].

To find the pH of the buffer solution, we can use the Henderson-Hasselbalch equation:
[tex]\[ \text{pH} = \text{p}K_a + \log \left( \frac{[A^-]}{[HA]} \right) \][/tex]

Step 1: Calculate [tex]\(\text{p}K_a\)[/tex]

[tex]\[ \text{p}K_a = -\log_{10}(K_a) \][/tex]

Given [tex]\(K_a = 3.0 \times 10^{-5}\)[/tex]:

[tex]\[ \text{p}K_a = -\log_{10}(3.0 \times 10^{-5}) \approx 4.522878745280337 \][/tex]

Step 2: Calculate the ratio of the conjugate base to the weak acid

[tex]\[ \frac{[A^-]}{[HA]} = \frac{0.480}{0.210} \approx 2.2857142857142856 \][/tex]

Step 3: Calculate the logarithm of the ratio

[tex]\[ \log_{10} \left( \frac{[A^-]}{[HA]} \right) = \log_{10}(2.2857142857142856) \approx 0.3590219426416697 \][/tex]

Step 4: Apply the Henderson-Hasselbalch equation

[tex]\[ \text{pH} = \text{p}K_a + \log \left( \frac{[A^-]}{[HA]} \right) \][/tex]
[tex]\[ \text{pH} = 4.522878745280337 + 0.3590219426416697 \approx 4.881900687922007 \][/tex]

So, the pH of the buffer solution is approximately [tex]\(4.8819\)[/tex].