Use Le Chatelier's Principle to predict how this reaction will shift if hydrogen gas [tex] (H_2) [/tex] is removed.

[tex]\[ N_2 (g) + 3H_2 (g) \rightleftharpoons 2NH_3 (g) \][/tex]

A. Shift in equilibrium for this reaction not caused by removing [tex] H_2 [/tex]
B. Shift right (in the forward direction) to make more products
C. Shift left (in the reverse direction) to make more reactants
D. Shift left (in the reverse direction) and then right (in the forward direction)



Answer :

To determine how the reaction will shift when hydrogen gas ([tex]$H_2$[/tex]) is removed, we can apply Le Chatelier's Principle. Le Chatelier's Principle states that if a system at equilibrium is disturbed by a change in concentration, pressure, or temperature, the system will shift its equilibrium position to counteract the disturbance.

Let's consider the reaction:
[tex]\[ N_{2(g)} + 3 H_{2(g)} \rightleftharpoons 2 NH_{3(g)} \][/tex]

This reaction is in equilibrium, meaning the rate of the forward reaction (forming [tex]$NH_3$[/tex]) is equal to the rate of the reverse reaction (forming [tex]$N_2$[/tex] and [tex]$H_2$[/tex]).

1. Removing [tex]$H_2$[/tex] Gas:
- Removal of [tex]$H_2$[/tex] decreases the concentration of one of the reactants.
- According to Le Chatelier's Principle, the system will attempt to counteract this change by producing more [tex]$H_2$[/tex].
- To produce more [tex]$H_2$[/tex], the equilibrium will shift towards the reverse direction (to the left).

2. Effect of the Shift:
- By shifting to the left, the system will convert some of the [tex]$NH_3$[/tex] back into [tex]$N_2$[/tex] and [tex]$H_2$[/tex].
- This process will increase the concentration of [tex]$H_2$[/tex] back towards the equilibrium concentration.

Therefore, when [tex]$H_2$[/tex] is removed, the equilibrium of the reaction shifts to the left (in the reverse direction) to make more [tex]$H_2$[/tex] and partially restore the balance.

Conclusion:
The removal of hydrogen gas ([tex]$H_2$[/tex]) will result in the equilibrium shifting to the left (in the reverse direction) to produce more [tex]$H_2$[/tex].

Thus, the correct answer is:
- Shift left (in the reverse direction) to make more reactants