The system below was at equilibrium and then some [tex]$O_2$[/tex] gas was removed from the container. What change will occur for the system?

[tex]2 SO_2(g) + O_2(g) \rightleftharpoons 2 SO_3(g) + 198 \, \text{kJ}[/tex]

A. The reaction will shift toward the products (right) and increase the concentration of [tex]$SO_3$[/tex].
B. The reaction will shift toward the products (right) and decrease the concentrations of [tex][tex]$SO_2$[/tex][/tex] and [tex]O_2$[/tex].
C. The reaction will shift toward the reactants (left) and increase the concentration of [tex]$SO_2$[/tex].
D. The reaction will not change because it was already at equilibrium.



Answer :

Certainly! Let's analyze the provided chemical system and the changes occurring when some [tex]\(O_2\)[/tex] gas is removed from the container.

The balanced chemical equation is:
[tex]\[ 2 \text{SO}_2(g) + \text{O}_2(g) \rightleftharpoons 2 \text{SO}_3(g) + 198\ \text{kJ} \][/tex]

This reaction is at equilibrium initially.

When a system at equilibrium experiences a change in concentration, pressure, or temperature, it will shift in a direction that counteracts the change. This principle is known as Le Chatelier's Principle.

In this scenario, [tex]\(O_2\)[/tex] gas is removed from the system. Let's analyze what happens step-by-step:

1. Change in Concentration:
- The removal of [tex]\(O_2\)[/tex] decreases its concentration in the system.

2. Applying Le Chatelier's Principle:
- According to Le Chatelier's Principle, the system will try to counteract the decrease in [tex]\(O_2\)[/tex] concentration.
- To do this, the reaction will shift in a direction that produces more [tex]\(O_2\)[/tex].

3. Direction of the Shift:
- In the given reaction:
[tex]\[ 2 \text{SO}_2(g) + \text{O}_2(g) \rightleftharpoons 2 \text{SO}_3(g) + 198\ \text{kJ} \][/tex]
- By shifting to the left (toward the reactants), the reaction will produce more [tex]\(O_2\)[/tex].

4. Impact on Concentrations:
- Shifting toward the reactants means converting some of the [tex]\(SO_3\)[/tex] back into [tex]\(SO_2\)[/tex] and [tex]\(O_2\)[/tex].
- As a result, the concentration of [tex]\(SO_2\)[/tex] will increase.
- The concentration of [tex]\(SO_3\)[/tex] will decrease.

Based on this analysis, the correct change that will occur in the system is:

The reaction will shift toward the reactants (left) and increase the concentration of SO