Final answer:
Gasoline, with its low boiling point, evaporates first during fractional distillation due to its high volatility.
Explanation:
During fractional distillation, the product with the lowest boiling point that evaporates first is gasoline. In the distillation process, the most volatile components, like gasoline blending components, which have a boiling point of 85-185 °F, condense at the top of the column, separating them from heavier components like diesel, kerosene, and asphalt.
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