Answer :
To determine the missing SMILES notations for the "Ether" and "Ketone" functional groups in the given table, follow the established notations for their structure diagrams.
1. Ether: Ethers have the general structure [tex]\( R-O-R' \)[/tex]. In SMILES notation, this translates to:
[tex]\[ \text{\texttt{[R]O[R]}} \][/tex]
2. Ketone: Ketones have the general structure [tex]\( R-\text{CO}-R' \)[/tex]. In SMILES notation, this translates to:
[tex]\[ \text{\texttt{[R]C(=O)[R]}} \][/tex]
Now, incorporating these notations into the table, we fill the "Ether" and "Ketone" columns appropriately:
[tex]\[ \begin{array}{|c|c|c|c|c|c|} \hline \text{Alcohol} & \text{Ether} & \text{Ketone} & \text{Aldehyde} & \text{Carboxylic Acid} & \text{Ester} \\ \hline \text{\texttt{[R]O}} & \text{\texttt{[R]O[R]}} & \text{\texttt{[R]C(=O)[R]}} & \text{\texttt{[R]C=O}} & \text{\texttt{[R]C(=O)O}} & \text{\texttt{[R]OC([R])=O}} \\ \hline \end{array} \][/tex]
Each SMILES notation now correctly matches its respective functional group.
1. Ether: Ethers have the general structure [tex]\( R-O-R' \)[/tex]. In SMILES notation, this translates to:
[tex]\[ \text{\texttt{[R]O[R]}} \][/tex]
2. Ketone: Ketones have the general structure [tex]\( R-\text{CO}-R' \)[/tex]. In SMILES notation, this translates to:
[tex]\[ \text{\texttt{[R]C(=O)[R]}} \][/tex]
Now, incorporating these notations into the table, we fill the "Ether" and "Ketone" columns appropriately:
[tex]\[ \begin{array}{|c|c|c|c|c|c|} \hline \text{Alcohol} & \text{Ether} & \text{Ketone} & \text{Aldehyde} & \text{Carboxylic Acid} & \text{Ester} \\ \hline \text{\texttt{[R]O}} & \text{\texttt{[R]O[R]}} & \text{\texttt{[R]C(=O)[R]}} & \text{\texttt{[R]C=O}} & \text{\texttt{[R]C(=O)O}} & \text{\texttt{[R]OC([R])=O}} \\ \hline \end{array} \][/tex]
Each SMILES notation now correctly matches its respective functional group.