To determine which reaction yields a salt with a pH less than 7, we need to analyze the nature of the reactants involved. Specifically, we have to consider whether each reactant is a strong or weak acid or base, and then determine the resulting pH of the salt produced:
1. KOH + HBr:
- KOH is a strong base.
- HBr is a strong acid.
- A reaction between a strong base and a strong acid yields a neutral salt (pH = 7).
2. HCOOH + KOH:
- HCOOH (formic acid) is a weak acid.
- KOH is a strong base.
- A reaction between a weak acid and a strong base produces a salt with pH greater than 7 (basic).
3. Ca(OH)2 + H2SO4:
- Ca(OH)2 (calcium hydroxide) is a strong base.
- H2SO4 (sulfuric acid) is a strong acid.
- A reaction between a strong base and a strong acid yields a neutral salt (pH = 7).
4. NH3 + HNO3:
- NH3 (ammonia) is a weak base.
- HNO3 (nitric acid) is a strong acid.
- A reaction between a weak base and a strong acid produces a salt with pH less than 7 (acidic).
Thus, the reaction that yields a salt with a pH less than 7 is:
NH3 + HNO3
So, the correct answer is: [tex]\( NH_3 + HNO_3 \)[/tex].